UV photoemission study on fullerene molecules deposited on defect-rich carbon surfaces |
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Authors: | M. Bü ttner,P. Reinke |
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Affiliation: | a Institut für Physik, Universität Basel, Klingelbergstr. 82, 4056 Basel, Switzerland b Department of Materials Science and Engineering, University of Virginia, Charlottesville, VA 22904-4145, USA |
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Abstract: | Submonolayers of C60 molecules have been deposited on different carbon substrates (pristine HOPG, argon-ion irradiated HOPG and amorphous carbon) and investigated by means of Ultraviolet Photoelectron Spectroscopy. The desorption behavior and spectral changes in the valence band were examined as a function of the sample temperature. Strong fullerene-substrate interaction (chemisorption) was observed on defect-rich surfaces (irradiated HOPG, a-C), indicated by binding energy shifts and broadening of C60 VB features. These chemisorbed species proved to be more resistant against temperature-induced desorption than usually observed for physisorbed molecules on pristine HOPG. The results presented here suggest that deposition of fullerenes on heated substrates might be a feasible method of surface nanostructuring by preferential chemisorption on defects. |
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Keywords: | Photoelectron spectroscopy Carbon Fullerenes Surface defects Graphite Chemisorption |
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