Intercalation of Dyes Containing SO3H Groups into Zn–Al Layered Double Hydroxide |
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| Authors: | Klára Melánová Ludvík Bene? Vítzslav Zima Jan Svoboda |
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| Affiliation: | (1) Joint Laboratory of Solid State Chemistry of Institute of Macromolecular Chemistry of Academy of Sciences and University of Pardubice, Studentsk? 84, 532 10 Pardubice, Czech Republic;(2) Institute of Macromolecular Chemistry of Academy of Sciences of the Czech Republic, Heyrovsk? Sq. 2, 162 06 Prague 6, Czech Republic; |
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| Abstract: | The intercalates of Naphthol Yellow S, Tropaeolin 000, and Tropaeolin 00 were prepared by heating [Zn0.67Al0.33(OH)2](CO3)0.165 · 0.5H2O with acidic forms of the dye solutions in an open reaction vessel. The intercalates were characterized by chemical and thermal analysis, X-ray powder diffraction and UV–VIS spectroscopy. A possible arrangement of the dye molecules in the intercalates was suggested on the basis of their chemical compositions and interlayer distances, by taking into account van der Waals dimensions of the guest molecules and by assuming that the structure of the host layers is not changed during the intercalation process. |
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