| 多孔金属片载杂多化合物膜的催化性能 |
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| 引用本文： | 邓谦,蔡铁军,彭振山,李大塘,张志锋,钟邦克. 多孔金属片载杂多化合物膜的催化性能[J]. 催化学报, 2000, 21(5): 481-483 |
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| 作者姓名： | 邓谦 蔡铁军 彭振山 李大塘 张志锋 钟邦克 |
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| 作者单位： | [1]湘潭师范学院化学系 [2]暨南大学化学系 |
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| 基金项目： | 湖南省自然科学基金;97 JJY 2070; |
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| 摘 要： | 用组合化学法合成了Ｃｕ１．３Ａｓ０．３ＰＶＭｏ１１高元杂多化合物，并用红外和差热－热重分析技术进行了表征；将高元杂多化合物制成高分子催化膜，用于几种醇的选择性催化氧化反应，结果表明，高元杂多化合物膜具有优异的催化性能，更坦 步探索了多孔金属片载杂多化合物膜催化技术的应用。
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| 关 键 词： | 醇氧化 |
| 文章编号： | 0253-9837(2000)05-0481-03 |
| 收稿时间： | 2000-10-25 |
Selective Oxidation of Alcohols over Heteropoly Compound Membrane Supported on Porous Titanium |
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| DENG Qian ,CAI Tiejun ,PENG Zhenshan ,LI Datang ,ZHANG Zhifeng ,ZHONG Bangke. Selective Oxidation of Alcohols over Heteropoly Compound Membrane Supported on Porous Titanium[J]. Chinese Journal of Catalysis, 2000, 21(5): 481-483 |
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| Authors: | DENG Qian CAI Tiejun PENG Zhenshan LI Datang ZHANG Zhifeng ZHONG Bangke |
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| Affiliation: | DENG Qian 1,CAI Tiejun 1,PENG Zhenshan 1,LI Datang 1,ZHANG Zhifeng 1,ZHONG Bangke 2 |
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| Abstract: | Heteropoly compound Cu 1.3 As 0.3 PVMo 11 was synthesized by the way of constituted chemistry. The compound was characterized by IR and DTA TG techniques. The heteropoly compound polymer membrane supported on porous titanium plate was prepared. Selective oxidation of several alcohols to aldehyde and ketone was carried out over the catalytic membrane. The results showed that the heteropoly compound membrane has high activity for the reaction and high selectivity for the object products. |
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| Keywords: | heteropoly compound membrane catalysis alcohol selective oxidation aldehyde ketone |
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