A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor |
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| Authors: | Claire Besson Sebastian Schmitz Kimberly M Capella Sivil Kopilevich Ira A Weinstock Paul Kögerler |
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| Affiliation: | Institut für Anorganische Chemie, RWTH Aachen University, 52074 Aachen, Germany. paul.koegerler@ac.rwth-aachen.de. |
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| Abstract: | A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid "guests" and azide functions previously attached to binding sites within the cavity of a {Mo(132)}-type Keplerate reproducibly gives a 2?:?1 ratio of 1,4- and 1,5-triazoles. |
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