Structure and optical anisotropy of pulsed-laser deposited TiO2 films for optical applications |
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Authors: | Nadya E Stankova Ivan G Dimitrov Petar A Atanasov |
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Institution: | a Institute of Electronics, Bulgarian Academy of Sciences, 72 Tsarigradsko chaussee, 1784 Sofia, Bulgaria b Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Acad. Georgi Bontchev str. Bl.11, 1113 Sofia, Bulgaria |
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Abstract: | The evolution of the crystal, the microstructural and the optical properties of pulsed-laser deposited TiO2 films, investigated by X-ray diffraction, atomic force microscopy, scanning electron microscopy, optical transmittance and m-line spectroscopy measurements are reported. The samples were grown on (0 0 1) SiO2 substrates at temperatures from 250 to 600 °C and oxygen pressures from 1 to 15 Pa. Crystalline films consisting of single anatase or anatase and rutile phases, were obtained at temperatures higher than 400 °C. A tendency toward columnar-like growth morphology was observed in the samples. Strong dependence of the optical properties on the surface roughness and the microstructure was determined. All films revealed single-mode waveguiding and optically anisotropic properties. |
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Keywords: | Single-mode TiO2 waveguiding films Pulsed-laser deposition Birefringence Optical gas sensors |
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