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Quantized Nanocrystalline CdTe Thin Films
引用本文:Jing Bo ZHANG,Yuan LIN,Yao LIU,Xu Rui XIAO* Center of Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080. Quantized Nanocrystalline CdTe Thin Films[J]. 中国化学快报, 2001, 0(8)
作者姓名:Jing Bo ZHANG  Yuan LIN  Yao LIU  Xu Rui XIAO* Center of Molecular Science  Institute of Chemistry  Chinese Academy of Sciences  Beijing 100080
作者单位:Jing Bo ZHANG,Yuan LIN,Yao LIU,Xu Rui XIAO* Center of Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080
摘    要:Size quantized nanocrystalline semiconductor thin films have attracted considerable interest in the photoelectrochemical studies1,2. In this paper, we report a pronounced size quantization in nanocrystalline CdTe thin films which is less extensively studied.Nanocrystalline CdTe thin films were electrodeposited on conducting glass by asymmetric rectangular pulse in dimethylsulfoxide solution containing 6 mmol/L Te, 0.75 mmol/L Cd(ClO4)2, 18 mmol/L triphenylphosphine and 0.1 mol/L LiClO4 a…


Quantized Nanocrystalline CdTe Thin Films
Jing Bo ZHANG,Yuan LIN,Yao LIU,Xu Rui XIAO Center of Molecular Science. Quantized Nanocrystalline CdTe Thin Films[J]. Chinese Chemical Letters, 2001, 0(8)
Authors:Jing Bo ZHANG  Yuan LIN  Yao LIU  Xu Rui XIAO Center of Molecular Science
Affiliation:Jing Bo ZHANG,Yuan LIN,Yao LIU,Xu Rui XIAO* Center of Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080
Abstract:Nanocrystalline CdTe thin films were prepared by asymmetric rectangular pulse electrodeposition in organic solution at 110(C. STM image shows a porous network morphology constructed by interconnected spherical CdTe crystallites with a mean diameter of 4.2 nm. A pronounced size quantization was indicated in the action and absorption spectra. Potentials dependence dual conductive behavior was revealed in the photocurrent-potential (I-V) curves.
Keywords:nanocrystalline CdTe thin film   asymmetric rectangular pulse electrodeposition   size quantization   dual conductive behavior
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