Synthesis of heterocyclic geminal nitro azides |
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| Authors: | D. V. Katorov G. F. Rudakov V. F. Zhilin |
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| Affiliation: | 1.D. Mendeleyev University of Chemical Technology of Russia,Moscow,Russian Federation |
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| Abstract: | The oxidative azidation reactions of C-nitro-substituted saturated heterocyclic compounds, viz., the nitro derivatives of oxetane, azetidine, 1,3-dioxane, tetrahydro-1,3-oxazine, and hexahydropyrimidine, were investigated. A novel representatives of the geminal nitro azides were prepared and their physicochemical properties were studied. The process of the formation of the geminal dinitro compounds upon oxidative azidation was analyzed. |
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