| 非水溶剂热法制备(001)面暴露的F/TiO2纳米晶及其光催化活性 |
| |
| 引用本文： | 蔡陈灵,王金果,曹锋雷,李和兴,朱建. 非水溶剂热法制备(001)面暴露的F/TiO2纳米晶及其光催化活性[J]. 催化学报, 2011, 32(5): 862-871. DOI: 10.1016/S1872-2067(10)60206-9 |
| |
| 作者姓名： | 蔡陈灵 王金果 曹锋雷 李和兴 朱建 |
| |
| 作者单位： | 上海师范大学化学系,上海,200234;上海师范大学化学系,上海,200234;上海师范大学化学系,上海,200234;上海师范大学化学系,上海,200234;上海师范大学化学系,上海,200234 |
| |
| 基金项目： | 国家自然科学基金(20825724,20907032); 上海市项目(0952nm00500,09520715300,07dz22303,10QA1405300,S30406,10YZ69)~~ |
| |
| 摘 要： | 采用非水体系溶剂热法制备了(001)面暴露的锐钛矿相F/TiO2纳米光催化剂.结果表明,F的掺杂对TiO2纳米单晶的形成影响很大.一方面,F离子作为晶面导向剂稳定(001)晶面,形成(001)面暴露的锐钛矿相TiO2;另一方面,F离子也起到稳定剂作用,抑制纳米粒子的快速生长.以光催化降解甲基橙为模型反应比较了不同F/T...
|
| 关 键 词： | 氟掺杂 二氧化钛 光催化 (001)晶面 甲基橙 |
Synthesis and Photocatalytic Activity of F/TiO2 Nanocrystals with Exposed (001) Facets via a Nonhydrolytic Solvothermal Route |
| |
| CAI Chenling,WANG Jinguo,CAO Fenglei,LI Hexing,ZHU Jian. Synthesis and Photocatalytic Activity of F/TiO2 Nanocrystals with Exposed (001) Facets via a Nonhydrolytic Solvothermal Route[J]. Chinese Journal of Catalysis, 2011, 32(5): 862-871. DOI: 10.1016/S1872-2067(10)60206-9 |
| |
| Authors: | CAI Chenling WANG Jinguo CAO Fenglei LI Hexing ZHU Jian |
| |
| Affiliation: | CAI Chenling,WANG Jinguo,CAO Fenglei,LI Hexing,ZHU Jian* Department of Chemistry,Shanghai Normal University,Shanghai,200234,China |
| |
| Abstract: | F/TiO2 nanocrystals with exposed(001)facets were synthesized by a nonhydrolytic solvothermal route.The influence of F ions on the formation process was investigated in detail.The F ions function as a crystal-face directing agent and a stabilizing agent.The photocatalytic activities of the F/TiO2 and commercial P25 samples were determined by the degradation of methyl orange.The influencing factors and active species in the degradation process are discussed after particular characterization and experiments wi... |
| |
| Keywords: | fluorine doping titania photocatalysis (001)facet methyl orange |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
