Rhus laccase catalysis and product characterization of 1,2-dimethoxyphenol in organic solutions |
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| Authors: | Yun Yang Wan Yu Min Du Tetsuo Miyakoshi |
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| Affiliation: | a State Key Laboratory of Petroleum Resources and Prospecting, Faculty of Natural Resources and Information Technology, China University of Petroleum, Beijing 102249, China;b Department of Industrial Chemistry, Meiji University, Higashi-mita, Tama-ku, Kawasaki 214, Japan;c School of Resource and Environment Science, Wuhan University, Wuhan 430079, China |
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| Abstract: | Dimethoxyphenol was a widely used substrate in determination of laccases activity. It was surprised, however, that the products of it had not been completely determined until now. Studies were thus conducted on Rhus laccase (RL) and immobilized Rhus laccase (IRL)-catalyzed oxidation of 2,6-dimethoxyphenol (DMP) in water-organic solvent systems. Only one product, 3,3',5,5'-tetramethoxy-l,l'-biphenyl-4,4'-diol (TMBP), was produced by RL catalysis, and it was thoroughly characterized by FT-IR, NMR and GC-MS, etc. |
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| Keywords: | Rhus laccase Laccase-catalyzed oxidation Organic solvents 2,6-Dimethoxyphenol |
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