Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization |
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| Authors: | Niibayashi Shota Hayakawa Hitoshi Jin Ren-Hua Nagashima Hideo |
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| Institution: | Dainippon Ink and Chemicals, Incorporated, 631 Sakado, Sakura, Chiba, Japan. |
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| Abstract: | Ionic iron complex (Me(3)tacn)(2)Fe(2)Cl(3)](+)(Me(3)tacn)FeCl(3)](-) (1), which is readily soluble in methanol, acted as a powerful catalyst in controlled radical polymerization of styrene and MMA, and showed promising features of removal from the resulting polymers and was reusable after recovery from the crude products. |
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