Reactions of criegee intermediates in the gas phase |
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| Authors: | S Hatakeyama H Akimoto |
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| Institution: | 1. National Institute for Environmental Studies, 305, Tsukuba, Ibaraki, Japan
2. Res. Center Adv. Sci. Technol., The University of Tokyo, 4-6-1, Komaba, Meguro-ku, 153, Tokyo, Japan
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| Abstract: | The reactions of Criegee intermediates in the gas phase are reviewed. These intermediates are formed by the reaction of olefins with ozone. In the gas phase Criegee intermediates have a biradical character. Initially they are formed as vibrationally hot species. After deactivation by collision with a third body, they can participate in bimolecular reactions with aldehydes, NOx, SO2, water, and so on. Reaction mechanisms are discussed. |
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