Formation of N-butane in the pyrolysis of ethylene [1] |
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| Authors: | B A Collings A L MacKenzie and P D Pacey |
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| Institution: | (1) Department of Chemistry, Dalhousie University, B3H 4J3 Halifax, Nova Scotia, Canada;(2) Present address: Diagnostic Chemicals Ltd., Charlottetown, Prince Edward Island, Canada |
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| Abstract: | Yields of n-C4H10 have been measured from the flow pyrolysis of C2H4 at 897 (±7) K. From 77 to 720 Torr the order of n-C4H10 formation was found to be 2.0±0.3 The rate constant for the reaction,
was estimated to be 2.4(±0.6)×10–4l mol–1s–1.
      -C4H10            C2H4 897 (±7)  .     -C4H10  77 720 2.0±0.3.   2C2H4 C2H3+C2H5 2,4 (±0,6)×10–4  –1–1.
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