| 苯乙烯相连的卟啉-三芳胺共轭体的合成及表征 |
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| 引用本文： | 薛金强,冯亚青,汪磊,吴玲卉.苯乙烯相连的卟啉-三芳胺共轭体的合成及表征[J].有机化学,2008,28(4):732-735. |
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| 作者姓名： | 薛金强 冯亚青 汪磊 吴玲卉 |
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| 作者单位： | 天津大学化工学院,天津,300072 |
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| 摘 要： | 以三芳胺甲醛和4-二乙氧基甲基苄基亚磷酸二乙酯为原料经Wittig-Horner反应制得化合物4-4-(N,N-二苯胺基)苯乙烯基]苯甲醛, 4-4-(N,N-二对甲苯胺基)苯乙烯基]苯甲醛和4-4-(N,N-二对甲氧基苯胺基)苯乙烯基]苯甲醛, 这些化合物与吡咯在丙酸中回流得到一类通过苯乙烯相连的卟啉-三芳胺共轭体, 并采用1H NMR, 13C NMR, MS及UV-vis对卟啉化合物的结构进行了表征.
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| 关 键 词： | 卟啉 三芳胺 共轭体 Wittig-Horner反应 苯乙烯 |
| 收稿时间： | 2007-6-11 |
| 修稿时间： | 2007年6月11日 |
Synthesis and Characterization of Conjugates ofPorphy-rin-triarylamine Linked by Styrene |
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| XUE Jin-Qiang,FENG Ya-Qing,WANG Lei,WU Ling-Hui.Synthesis and Characterization of Conjugates ofPorphy-rin-triarylamine Linked by Styrene[J].Chinese Journal of Organic Chemistry,2008,28(4):732-735. |
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| Authors: | XUE Jin-Qiang FENG Ya-Qing WANG Lei WU Ling-Hui |
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| Institution: | School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072) |
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| Abstract: | The compounds 4-4-(N,N-diphenylamino)styryl]benzaldehyde, 4-4-(N,N-di-p-tolylamino)- styryl]benzaldehyde and 4-4-(N,N-di-4-methoxyphenylamino)styryl]benzaldehyde were obtained by a Wit-tig-Horner reaction of 4-diarylaminobenzaldehyde with diethyl 4-(diethoxymethyl)benzylphosphonate, then a series of new porphyrin-triarylamine conjugates linked by styrene bridges were synthesized by refluxing compounds 4 and pyrrole in propionic acid and characterized by 1H NMR, 13C NMR, MS and UV-vis techniques. |
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| Keywords: | porphyrin triarylamine conjugate Wittig-Horner reaction styrene |
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