| COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR |
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| 作者姓名： | 陈传福 任长玉 习复 |
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| 作者单位： | Institute of Chemistry，Academia Sinica，Beijing 100080，Institute of Chemistry，Academia Sinica，Beijing 100080，Institute of Chemistry，Academia Sinica，Beijing 100080 |
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| 摘 要： | The copolymerization process of triphenylmethyl methacrylate (TrMA) and methylmethacrylate (MMA) using chiral anionic complex initiator (-) SP-FlLi (Scheme 1) has beenstudied in toluene and THF, respectively. The copolymer obtained in toluene possessed muchhigher specific rotation than that in THF. These copolymers have shown a tendency to a random and a like alternating structure, respectively.
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| 收稿时间： | 1993-04-30 |
COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR* |
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| CHEN Chuanfu,REN Changy,XI Fu.COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR[J].Chinese Journal of Polymer Science,1994,0(2):190-192. |
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| Authors: | CHEN Chuanfu REN Changy XI Fu |
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| Institution: | Institute of Chemistry; Academia Sinica; Beijing |
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| Abstract: | The copolymerization process of triphenylmethyl methacrylate (TrMA) and methylmethacrylate (MMA) using chiral anionic complex initiator (-) SP-FlLi (Scheme 1) has beenstudied in toluene and THF, respectively. The copolymer obtained in toluene possessed muchhigher specific rotation than that in THF. These copolymers have shown a tendency to a random and a like alternating structure, respectively. |
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