Novel reducing properties of a series of lanthanoid metals in the presence of SmI2 |
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| Authors: | Yuri Tomisaka Aya Yoshimura Akihiro Nomoto Motohiro Sonoda Akiya Ogawa |
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| Institution: | 1. Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka, 599-8531, Japan
2. Advanced Materials Research Laboratory, KRI, Inc., Kyoto Research Park, 134 Chudoji Minami-machi, Shimogyo-ku, Kyoto, 600-8813, Japan
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| Abstract: | The reduction of dodecyl iodide, as model compound, with a series of lanthanoid (Ln) metals in the presence of catalytic amounts of samarium diiodide (SmI2) has been investigated in detail. The reducing activity of SmI2/Ln and the kinds of reduced products were found to be dependent on the individual Ln, but not on SmI2. |
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