A New Rearrangement Reaction of 2-Phenyl Substituted Benzothiazepine with Ethoxycarbonyl Carbene─Mechanism of the Reaction and Structure of the Product 期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

A New Rearrangement Reaction of 2-Phenyl Substituted Benzothiazepine with Ethoxycarbonyl Carbene─Mechanism of the Reaction and Structure of the Product

作者姓名：	Hong Zhong WANG Dan YAO Ruo Xi LAN Jia Xi XU Sheng JIN (College of Chemistry and Molecular Engineering Peking University Beijing 100871)

作者单位：	College of Chemistry and Molecular Engineering，Peking University，Beijing 100871

摘要：	Intheprevi0usaFticlesl-2wehavereportedthatthereacti0n0fbenz0diazepinewithethoxycarbonylcarbenemayobtainnormal[2 l]cycIoadditi0npr0ductsregardlessthe2-substitUentismethyl0rphenyl.Howeverunderthesamec0nditi0nsthereaction0fbenzothiazepinewithethoxycarbonylcarbeneunderwentrearrangementreacti0n.Forexample,whenthe2-substituentismethyl,thereacti0nofbenzothiazepinewithethoxycarbonylcarbenegivearing-openingproductIIatroomorhightemperature'.Whenthe2-substituentisphenyl,weunexpectedlyfoundan0thernewrea…
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