| 卟啉类化合物与碳纳米材料非共价相互作用的研究进展 |
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| 引用本文： | 张达奇,杨娟,李彦.卟啉类化合物与碳纳米材料非共价相互作用的研究进展[J].中国科学:化学,2014(2):216-228. |
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| 作者姓名： | 张达奇 杨娟 李彦 |
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| 作者单位： | 北京分子科学国家实验室 稀土材料化学及应用国家重点实验室 纳米器件物理与化学教育部重点实验室 北京大学化学与分子工程学院,北京100871 |
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| 基金项目： | 国家自然科学基金(21005004,21125103,11179011);国家重点基础研究发展计划(973计划,2011CB933003)资助 |
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| 摘 要： | 卟啉-碳纳米非共价复合材料在光电器件、催化和生物医药等领域均具有重要的研究意义和广泛的应用前景.本文综述了卟啉类化合物与碳纳米材料的非共价相互作用的研究进展,并重点介绍了卟啉的结构设计对碳纳米材料结构的依赖性和进而表现出的选择性,包括对富勒烯碳笼大小、旋光性的依赖性,对单壁碳管导电性、管径、手性、旋光性的依赖性,以及对石墨烯氧化程度的依赖性等.
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| 关 键 词： | 卟啉 碳纳米材料 非共价相互作用 富勒烯 碳纳米管 石墨烯 |
Recent progress in non-covalent interactions between porphyrin and carbon nanomaterials |
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| ZHANG DaQi,YANG Juan,LI Yan.Recent progress in non-covalent interactions between porphyrin and carbon nanomaterials[J].Scientia Sinica Chimica,2014(2):216-228. |
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| Authors: | ZHANG DaQi YANG Juan LI Yan |
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| Institution: | ( Beijing National Laboratory for Molecular Sciences; State Key Laboratory of Rare Earth Materials Chemistry and Applications; Key Laboratory for the Physics and Chemistry of Nanodevices; College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China) |
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| Abstract: | Non-covalent composites of porphyrin-carbon nanomaterials play an important role in both research and application areas of optoelectronic devices, catalysis, bio-medicine, etc. This review covers the recent process in non-covalent interactions between porphyrins and carbon nanomaterials, and focuses on the structural dependence and selectivity of carbon nanomaterials by designing the porphyrin structure. The structural dependence includes cage size and optical activity for fullerenes, conductivity, diameter, chirality and optical activity for single-walled carbon nanotubes, and degree of oxidation for graphene. |
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| Keywords: | porphyrin carbon nanomaterials non-covalent interaction fullerene carbon nanotubes graphene |
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