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聚乙烯基胺包裹Fe3O4@SiO2磁性微球用于Knoevenagel缩合(英文)
作者姓名:Farzad Zamani  Elham Izadi
作者单位:a Department of Chemistry, Shahreza Branch, Islamic Azad University, Shahreza 31186145, Isfahan, Iran;
b Laboratory of Applied Chemistry, Central Laboratory Complex, Isfahan Science and Technology Town, Isfahan University of Technology, Isfahan 8415683111, Iran
摘    要:

收稿时间:2013-07-20

Polyvinyl amine coated Fe3O4@SiO2 magnetic microspheres for Knoevenagel condensation
Farzad Zamani,Elham Izadi.Polyvinyl amine coated Fe3O4@SiO2 magnetic microspheres for Knoevenagel condensation[J].Chinese Journal of Catalysis,2014,35(1):21-27.
Authors:Farzad Zamani  Elham Izadi
Institution:a Department of Chemistry, Shahreza Branch, Islamic Azad University, Shahreza 31186145, Isfahan, Iran;
b Laboratory of Applied Chemistry, Central Laboratory Complex, Isfahan Science and Technology Town, Isfahan University of Technology, Isfahan 8415683111, Iran
Abstract:Polyvinyl amine coated Fe3O4@SiO2 composite microspheres with a core-shell structure were prepared and employed as a magnetic catalyst for Knoevenagel condensation under mild conditions. The catalyst can be readily recovered using a magnet and reused several times without loss in activity or selectivity. The performance of the magnetic base catalyst was compared with that of polyvinyl amine functionalized mesoporous SBA-15, which showed that the magnetic nanoparticles gave improved reaction rate and yield.
Keywords:Basic magnetic catalyst  Fe3O4 nanoparticle  Polyvinyl amine  Knoevenagel condensation
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