Exchange kinetics of amino acid anions in solutions of ternary copper(II) complexes with diethylenetriamine |
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| Authors: | E. L. Gogolashvili V. G. Shtyrlin A. V. Zakharov |
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| Affiliation: | (1) State University, 420008 Kazan, USSR |
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| Abstract: | Rate constants for the chemical exchange of some amino acid anions in solutions of copper(II) ternary complexes with diethylenetriamine have been determined by the NMR method. The coordination of amino acid anions in ternary and binary species is different and ligand substitution in the Cu(II) complexes follows an associative mechanism.
                        -  (II)  .  -   (II).
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