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Optimizing biomimetic gelators constructed from amino acid building blocks
Authors:Coates Ian A  Hirst Andrew R  Smith David K
Affiliation:Department of Chemistry, University of York, Heslington, York YO10 5DD, UK.
Abstract:This paper reports the use of a range of amino acids to construct diverse gelators, employing structures in which Boc-protected amino acids are attached to either end of an aliphatic diamine spacer chain. The choice of amino acid determines whether nanoscale self-assembly takes place and controls the properties of the resultant material, while the function of the amino acid (e.g., the optical properties of tryptophan) is translated into the self-assembled nanostructured gel.
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