Reductive Hydroformylation of Isosorbide Diallyl Ether |
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| Authors: | Jrmy Ternel Adrien Lopes Mathieu Sauthier Clothilde Buffe Vincent Wiatz Herv Bricout Sbastien Tilloy Eric Monflier |
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| Institution: | 1.University of Artois, CNRS, Centrale Lille, University of Lille, UMR 8181–UCCS–Unité de Catalyse et Chimie du Solide, F-62300 Lens, France; (J.T.); (A.L.); (H.B.); (E.M.);2.University of Lille, CNRS, Centrale Lille, ENSCL, University of Artois, UMR 8181, Unité de Catalyse et Chimie du Solide, F-59000 Lille, France;3.Roquette Frères, 1 Rue de la Haute Loge, F-62136 Lestrem, France; (C.B.); (V.W.) |
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| Abstract: | Isosorbide and its functionalized derivatives have numerous applications as bio-sourced building blocks. In this context, the synthesis of diols from isosorbide diallyl ether by hydrohydroxymethylation reaction is of extreme interest. This hydrohydroxymethylation, which consists of carbon-carbon double bonds converting into primary alcohol functions, can be obtained by a hydroformylation reaction followed by a hydrogenation reaction. In this study, reductive hydroformylation was achieved using isosorbide diallyl ether as a substrate in a rhodium/amine catalytic system. The highest yield in bis-primary alcohols obtained was equal to 79%. |
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| Keywords: | catalysis hydroformylation hydrogenation rhodium tandem reaction |
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