Heteronuclear decoupling interference during symmetry-based homonuclear recoupling in solid-state NMR |
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Authors: | Marin-Montesinos Ildefonso Brouwer Darren H Antonioli Giancarlo Lai Wai Cheu Brinkmann Andreas Levitt Malcolm H |
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Institution: | School of Chemistry, University of Southampton, Southampton SO17 1BJ, UK. |
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Abstract: | We examine the influence of continuous-wave heteronuclear decoupling on symmetry-based double-quantum homonuclear dipolar recoupling, using experimental measurements, numerical simulations, and average Hamiltonian theory. There are two distinct regimes in which the heteronuclear interference effects are minimized. The first regime utilizes a moderate homonuclear recoupling field and a strong heteronuclear decoupling field; the second regime utilizes a strong homonuclear recoupling field and a weak or absent heteronuclear decoupling field. The second regime is experimentally accessible at moderate or high magic-angle-spinning frequencies and is particularly relevant for many realistic applications of solid-state NMR recoupling experiments to organic or biological materials. |
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Keywords: | Symmetry-based recoupling Decoupling Double-quantum NMR Magic-angle spinning Average Hamilonian theory |
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