Studies of the composition and catalytic properties of supported catalysts prepared through halide-substituted titanium and zirconium benzyl complexes |
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| Authors: | G A Nesterov V A Zakharov Yu I Yermakov K -H Thiele M Schlegel and H Drevs |
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| Institution: | (1) Institute of Catalysis, Novosibirsk, USSR;(2) T. H.,  Carl Schorlemmer , Leuna-Merseburg, DDR |
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| Abstract: | Composition and catalytic properties in ethylene polymerization of supported systems prepared via the interaction of Ti(CH2C6H5)3X (X=F, Cl, Br) and Zr(CH2C6H5)2Cl2 complexes with silica and alumina have been studied. Halide addition to benzyl complexes decreases the polymer molecular mass.
                       ,  Ti(CH2C6H5)3X (X=F, Cl, Br) Zr(CH2C6H5)2Cl2 SiO2 Al2O3.  ,       .
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