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Structural control and magnetic properties of electrodeposited Co nanowires
Authors:Xue Wei Wang  Guang Tao Fei  Peng Tong  Xi Jin Xu  Li De Zhang
Institution:

aKey Laboratory of Materials Physics, Institute of Solid State Physics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, P.O. Box 1129, Hefei 230031, PR China

Abstract:Co nanowires with a preferred orientation were fabricated by direct current electrodeposition into the pores of porous anodic alumina membrane, and the structure of Co nanowires was studied by X-ray diffraction and high-resolution transmission electron microscopy with selected-area electron diffraction. It is found that the crystal structure of Co nanowires lies on the deposition potential. When electrodeposition is performed far from equilibrium conditions, i.e., at a high potential, face-centered cubic Co nanowires are deposited, while hexagonal close packing Co nanowires are formed at the low potential. The experimental results indicate that the orientation of the nanowires has effects on the coercivity for both hexagonal close packing (hcp) and face-centered cubic (fcc) Co.
Keywords:A1  Nanostructures  A2  Electrochemical growth  B1  Metals  B2  Magnetic materials
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