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Photochemical asymmetric synthesis of phenyl-bearing quaternary chiral carbons using chiral-memory effect on beta-hydrogen abstraction by thiocarbonyl group |
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| Authors: | Sakamoto Masami Kawanishi Hiroya Mino Takashi Kasashima Yoshio Fujita Tsutomu |
| Affiliation: | Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, Yayoi-cho, Inage-ku, Chiba, 263-8522, Japan. sakamotom@faculty.chiba-u.jp |
| Abstract: | Quaternary chiral carbons were effectively generated from tertiary chiral carbons via photochemical intramolecular beta-hydrogen abstraction reaction of thioimides involving the highly-controlled chiral-memory effect. |
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