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Interaction of (1-phenylethyl)indole-2-carbonitrile with C-nucleophiles |
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| Authors: | N. E. Golantsov A. V. Karchava M. A. Yurovskaya |
| Affiliation: | (1) Chemical Faculty, M. V. Lomonosov Moscow State University, Moscow, 119992, Russia |
| Abstract: | Methods of obtaining ketones and enamino esters have been developed on the basis of reactions of 1-(1-phenylethyl)indole-2-carbonitrile with organomagnesium and organozinc compounds. Removal of a benzyl group from the indole nitrogen atom by the Grignard reagent has been discovered. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1179–1183, August, 2006. |
| Keywords: | enamino esters 2-propionylindole 1-(1-phenylethyl)indole-2-carbonitrile [1-(1-phenylethyl)-2-indolyl]-1-propanone ethyl ester of Z-3-amino-3-[1-(1-phenylethyl)-2-indolyl]acrylic acid Blaise reaction interactions with C-nucleophiles N-dibenzylation |
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