Double clathrate hydrates of cross-linked tetrabutylammonium polyacrylate and noble gases at high pressures |
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| Authors: | E Ya Aladko E G Larionov A Yu Manakov I S Terekhova |
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| Institution: | 1. A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrent’ev Av. 3, 630090, Novosibirsk, Russian Federation
2. Novosibirsk State University, Pirogova Str. 2, Novosibirsk, 630090, Russian Federation
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| Abstract: | Temperatures of hydrate decomposition were measured by means of the differential thermal analysis at a pressures up to 800–900 Mpa in the systems: cross-linked tetrabutylammonium polyacrylate–water and cross-linked tetrabutylammonium polyacrylate–water–noble gas (He, Ne, Ar, Kr, Xe). The effect of the deformation of D- cavities of the hydrates on the temperature of their decomposition is discussed on the basis of the experimental data. |
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