Synthesis and study of binuclear calix[4]arene Schiff base Co(II) complexes as catalyst in the presence of PhIO for the catalytic oxidation of olefin |
| |
Authors: | Ravindra V Patel Jayesh G Panchal Shobhana K Menon |
| |
Institution: | 1. Department of Chemistry, School of Sciences, Gujarat University, Ahmedabad, 380009, India
|
| |
Abstract: | The binuclear Co(II) complexes of calix4]arene substituted 2-vanillin (R1) and 2-hydroxy naphthaldimine (R2), Schiff bases (Co2L1 and Co2L2) have been synthesized, characterized and employed as models to mimic monooxygenase in the catalytical oxidation of olefins. The kinetic mathematical model (oxygen rebound mechanism) for olefin cleavage catalyzed by the complexes has been proposed. The results show that, compared to the calix4]arene-free analogous, the mono and multinuclear complexes of calix4]arene Schiff bases as catalyst exhibit high activity in the olefin catalytic oxidation. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|