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New fluorescent sensor for antimony and transition metal cations based on rhodamine amide-arm homotrioxacalix[3]arene
Authors:Chong Wu  Wen-Juan Zhang  Xi Zeng  Lan Mu  Sai-Feng Xue  Zhu Tao  Takehiko Yamato
Institution:1. School of Chemistry and Chemical Engineering, Guizhou University, 550003, Guiyang, Peoples Republic of China
2. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, 550025, Guiyang, Peoples Republic of China
3. Department of Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi 1, Saga-shi, Saga, 840-8502, Japan
Abstract:A new fluorescent sensor 1 based on the rhodamine amide-armed homotrioxacalix3]arene was synthesized, and its sensing behavior toward metal ions was investigated by UV–vis and fluorescence spectroscopies. Upon the addition of metal cations (Sb3+, Fe3+, Ni2+), a significant fluorescent enhancement in the range of 500–600 nm and colorimetric change was observed.
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