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Note on the quantum displacement of the critical point
Authors:T S Nilsen  P C Hemmer
Institution:(1) Institutt for Teoretisk Fysikk, Norges Tekniske Høgskole, Trondheim, Norway
Abstract:The quantum corrections to the law of corresponding states are studied by calculating the critical pressure, temperature, and density to first order in Planck's constanth on an exactly soluble model. The ratio of the critical parameters to the corresponding classical values are found to be (p c/p c 0)1/2=rgrc/rgrc 0 = Tc/Tc 0 = 1–0.67Lambda, withLambda=hrgr c 1/3(mkT c)–1/2. The critical ratio is independent ofh to first order. The results are compared with critical data for noble gases and hydrogen isotopes.
Keywords:Critical point  Equation of state  Quantum effects  Corresponding states  Fluids
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