Macrocycle-mediated separation of Eu from trivalent lanthanide cations in a modified thin-sheet-supported liquid membrane system |
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Authors: | C.Y. Zhu R.M. Izatt |
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Affiliation: | Department of Chemistry, Brigham Young University, Provo, Utah 84602 U.S.A. |
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Abstract: | Macrocycle-mediated transport of Eu3+ and Eu2+ from an aqueous solution through a modified thin-sheet-supported liquid membrane has been studied and compared with that of Sr2+, Gd3+ and Nd3+. Transport of Eu2+ was found to be more effective than that of trivalent lanthanide cations using bis (1-hydroxylheptyl)DC18C6 as the membrane carrier. The flux of Eu2+ was similar to that of Sr2+ while those of Eu3+, Gd3+ and Nd3+ were almost identical and much less than that of Sr2+. |
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