Norditerpenoid alkaloids from Aconitum septentrionale K. |
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Authors: | E. D. Khairitdinova E. M. Tsyrlina L. V. Spirikhin A. A. Balandina Sh. K. Latypov M. S. Yunusov |
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Affiliation: | (1) Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia;(2) Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia |
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Abstract: | Two new alkaloids, Septonine (C35H44N2O9) and Septontrionine (C25H39NO6) were isolated from the roots of Aconitum septentrionale K. According to the 1H and 13C NMR, IR, and mass spectra, Septonin and Septontrionin were assigned the structures of 20-ethyl-7-hydroxy-1α,14α,16β-trimethoxy-6-oxo-17(7→8)abeoaconitan-4-ylmethyl 2-(2,5-dioxopyrrolidin-l-yl)benzoate and 20-ethyl-7-hydroxy-1α,14α,16β-trimethoxy-4-methoxymethyl-17(7→8)abeoaconitan-6-one, respectively. |
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