Synthesis and crystal structure of 3,4-trans-4, 5-trans-2-amino-3-cyano-1,3-dimethyloxycarbonyl-4, 5-di(3,4-methyl-enedioxylphenyl) cyclopentene |
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Authors: | Daqing Shi Hong Zhao Xiangshan Wang Shujiang Tu |
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Institution: | (1) Department of Chemistry, Xuzhou Normal University, Xuzhou, 221009, People's Republic of China |
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Abstract: | The 3,4-trans-4,5-trans-2-amino-3-cyano-1,3-dimethyloxycarbonyl-4,5-di-(3,4-methyl-enedioxylphenyl) cyclopentene has been synthesized and characterized by IR, 1H NMR, Elemental analysis, and X-ray crystallography. It crystallizes in the monoclinic space group P21/n, with a = 10.936(3) Å, b = 10.142(3) Å, c = 20.001(4) Å, = 93.81(2)°, and D
calc = 1.390 g cm–3 for Z = 4. X-ray analysis reveals that the phenyl groups and the alkoxyl carbonyl group are in the equatorial positions. The dihedral angles between the phenyl groups and the central five-membered ring are 73.08° and 62.15°. In addition, there are intermolecular hydrogen bonds in the crystal lattices. |
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Keywords: | Crystal structure functional cyclopentene synthesis |
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