Synthesis of Nitroanilines Catalyzed by Horseradish Peroxidase in the Presence of NaNO2 and H2O2 |
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Authors: | LIU Cong DAI Rong-ji LIN Jie SUN Jian-hua CHEN Shi DENG Yu-lin |
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Affiliation: | School of Life Science, Beijing Institute of Technology, Beijing 100081, P. R. China |
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Abstract: | The synthesis of nitroanilines catalyzed by horseradish peroxidase(HRP) in the presence of sodium nitrite and hydrogen peroxide was investigated. o-Nitroaniline and p-nitroaniline were found in the nitrated products. 2-Aminotoluene and 4-aminotoluene could also be nitrated to give corresponding nitrated products. This protocol has great potentials to open new avenues useful for the synthesis of nitroaniline and its derivatives. |
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Keywords: | Nitroaniline Horseradish peroxidase Phenylamine Nitration Enzyme |
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