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High-temperature High-pressure Hydrothermal Synthesis of Dy3+-doped YNbO4 Single Crystal and Its Luminescence Properties
基金项目:the National Natural Science Foundation of China
摘    要:Single crystal Dy3+ doped YNbO4phosphors were prepared via a high-temperature high-pressure hydrothermal procedure. Under excitation at 270 nm, the Dy3+-doped YNbO4 phosphor shows bright white emission, which is composed of two strong bands at 492 and 576 nm corresponding to the characteristic 4F9/2→6H15/2 and aF9/2→6H13/2 transitions of Dy3+, respectively. The dominant band was observed at 352 nm, which corresponds to the 6H15/2→6p7/2 transition of Dy3+. Nearly white light was achieved at 2ex 270, 310 and 388 nm and the CIE(International Commission on Illumination) values were (0.3135, 0.3421), (0.3088, 0.3380) and (0.3146, 0.3296), respectively.

关 键 词:高温高压  水热法  发光性能  掺杂  单晶  国际照明委员会  合成  激发波长
收稿时间:2013-03-04

High-temperature High-pressure Hydrothermal Synthesis of Dy3+-doped YNbO4 Single Crystal and Its Luminescence Properties
Authors:YANG Min  LI  Qi-liang WANG  Ying LIU  Xiao-yang WANG  Xiao-feng
Institution:State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, P. R. China
Abstract:Single crystal Dy3+ doped YNbO4 phosphors were prepared via a high-temperature high-pressure hydrothermal procedure. Under excitation at 270 nm, the Dy3+-doped YNbO4 phosphor shows bright white emission, which is composed of two strong bands at 492 and 576 nm corresponding to the characteristic 4F9/26H15/2 and 4F9/26H13/2 transitions of Dy3+, respectively. The dominant band was observed at 352 nm, which corresponds to the 6H15/26P7/2 transition of Dy3+. Nearly white light was achieved at λex 270, 310 and 388 nm and the CIE(International Commission on Illumination) values were (0.3135, 0.3421), (0.3088, 0.3380) and (0.3146, 0.3296), respectively.
Keywords:Dy-YNbO4  Single crystal  High-temperature high-pressure  Hydrothermal  Luminescence
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