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Chemical Modifiers in Modern Electrothermal Atomic Absorption Spectrometry
Authors:A. B. Volynskii
Affiliation:(1) Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow, 119991, Russia
Abstract:The role of chemical modifiers in modern electrothermal atomic absorption spectrometry is considered. It is demonstrated that the selection of the optimal chemical modifier largely determines the potential of the method for the analysis of complex samples. The mechanisms of the action of nitric and oxalic acids; magnesium, nickel, and ammonium nitrates; high-melting carbides; organic compounds, and some other; chemical modifiers are briefly discussed. The most promising fields of application of these modifiers are outlined.
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