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Cu(I)-catalyzed allylic amination of olefins |
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| Authors: | Gregg A Hogan August A Gallo Kenneth M Nicholas Radhey S Srivastava |
| Institution: | aDepartment of Chemistry, University of Louisiana at Lafayette, Lafayette, LA 70504, USA bDepartment of Chemistry and Biochemistry, University of Oklahoma, Norman, OK 73019, USA |
| Abstract: | The copper(I) complex Cu(CH3CN)4]PF6 catalyzes the allylic amination of alkenes by aryl hydroxylamine in fair to moderate yields. Unsymmetrical alkenes react with high regioselectivity with N-functionalization occuring at the less substituted vinylic carbon. Trapping experiments indicate that free PhNO is not an intermediate in these reactions. |
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