An unprecedented, reversible coordination mode rearrangement: eta3(B-H) vs.eta1(Sn) stanna-closo-dodecaborate coordination |
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| Authors: | Gädt Torben Wesemann Lars |
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| Institution: | Institut für Anorganische Chemie der Universit?t Tübingen, Germany. |
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| Abstract: | The synthesis of the ruthenium stanna-closo-dodecaborate complex Bu(3)MeN](2)Ru(dppb)(MeCN)(2)(SnB(11)H(11))(2)] by an unprecedented, reversible eta(3)(B-H) to eta(1)(Sn) rearrangement of Bu(3)MeN](2)Ru(dppb)(SnB(11)H(11))(2)] is described and the product is characterized by multinuclear NMR spectroscopy and single-crystal X-ray diffraction. |
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