2H NMR measurements of the molecular orientational ordering in a reentrant liquid-crystalline mixture |
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Authors: | NAP Vaz Z Yaniv JW Doane |
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Institution: | Liquid Crystal Institute and Department of Physics, Kent State University, Kent, Ohio 44242, USA |
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Abstract: | Deuterium NMR measurements of the molecular orientational ordering (nematic order) are reported for a reentrant binary mixture of some alkoxy-eyanobiphenyls (nOCB) to which small amounts of perdeuterated p-xylene have been added. The results indicate that the degree of orientational order is enhanced at the smectic A to reentrant nematic phase transition. This effect is shown to be in agreement with the predictions of a Landau-type theory of the reentrant phase transition where-by this phase transition is explained as the result of a coupling between the smectic and the nematic order parameters. |
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