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Flourescence lifetimes anf excitation spectra of the jet-cooled HNO radical |
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| Authors: | Kinichi Obi Yutaka Matsumi Yasuaki Takeda Shinya Mayama Hajime Watanabe Soji Tsuchiya |
| Institution: | Department of Chemistry, Tokyo Institute of Technology, Ohokayama, Meguroko. Tokyo 152, Japan;Department of Pure and Applied Sciences, College of General Education, University of Tokyo, Komaba, Meguroku, Tokyo 153, Japan |
| Abstract: | The new nozzle assembly using Hg-photosensitized reaction has been developed to obtained a jet-cooled radical beam. This technique was applied to produce a HNO radical beam. Laser-induced flourescence excitation spectra were obtained for the 1A″ — 1A′ system. Time-resolved measurements yielded fluorescence lifetimes of 22–29 μs for single rovibronic levels of HNO. |
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