Service de Spectros?opie Moléculaire en Milieu Condensé, Laboratoire de Recherches Physique, associé au CNRS, Université Pierre et Marie Curie, 4 place Jussieu, Tour 22, 7530 Paris Cedex 05, France
Abstract:
A model of vibrational dephasing with motional narrowing by the librational motions of the molecules in their cages is tested on the example of the ν6 degenerate infrared fundamental of liquid CD3l at room temperature.