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The exciplexes of thioindigo with durene and hexamethylbenzene and their influence on photoisomerization
Authors:E Birckner  R Paetzold  MV Kozmenko  MG Kuzmin
Institution:Sektion Chemie der Friedrich-Schiller Universität, DDR-69, Jena GDR;Faculty of Chemistry, Moscow State University, Moscow 117234, USSR
Abstract:The quenching of thioindigo flourescence by hexamethylbenzene and durene in solvents of low polarity is accompanied by exciplex emission. The exciplex formation and dissociation rate constants and its photophysical properties are determined. Thiondigo photoisomerization can proceed via exciplex formation.
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