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The hypersensitive Δguδu) ← Σg transition of the uranyl ion
Authors:Colin D Flint
Institution:Department of Chemistry. Birkbeck College, Malet Street, London WC1E 7HX, UK
Abstract:The Δguδu) ← Σgu)2 transition of the uranyl ion which corresponds to an electron transfer for a weakly bonding oxygen orbital to a non-bonding uranium 5f±2 orbital has characteristics similar to so-called hypersensitive 4f-4f transitions of the lanthanide ions.
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