The hypersensitive Δg(σuδu) ← Σg transition of the uranyl ion |
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Authors: | Colin D Flint |
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Institution: | Department of Chemistry. Birkbeck College, Malet Street, London WC1E 7HX, UK |
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Abstract: | The Δg(σuδu) ← Σg(σu)2 transition of the uranyl ion which corresponds to an electron transfer for a weakly bonding oxygen orbital to a non-bonding uranium 5f±2 orbital has characteristics similar to so-called hypersensitive 4f-4f transitions of the lanthanide ions. |
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