Reactive and non-reactive quenching of O(1D2) by COF2 |
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Authors: | PH Wine AR Ravishankara |
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Institution: | Molecular Sciences Group, Engineering Experiment Station, Georgia Institute of Technology, Atlanta, Georgia 30332, USA |
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Abstract: | Quenching of O(1D2) by COF2 has been investigated by time-resolved resonance fluorescence monitoring of the product O(3PJ) following 248 nm pulsed laser photolysis of O3. The rate constant for total removal of O(1D2) by COF2 is (7.4 ± 1.2) × 10?11 cm3 molecule?1 s?1. 71 ± 7% of the quenching interactions result in formation of O(3PJ). |
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