Alkenoxy radicals in gas-phase reactions of alkenes with oxygen atoms or ozone |
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| Authors: | Richard I Martinez |
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| Institution: | Chemical Kinetics Division, Center for Chemical Physics, National Bureau of Standards, Washington, DC 20234, USA |
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| Abstract: | Observations in the O3 + trans-2-butene reaction system and in the O + trans-2-butene + O2 reaction system suggest the intermediacy of alkenoxy radicals. A mechanism is proposed for the production of Cn and Cm (m <n) alkenoxy radicals by the reaction of CnH2n alkenes with oxygen atoms or with ozone. |
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