The effect of a polymeric additive on the evaporation of organic aerocolloidal droplets |
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Authors: | J F Widmann C M Heusmann E James Davis |
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Institution: | (1) Department of Chemical Engineering Box 351750 University of Washington Seattle, WA 98195-1750 USA, US |
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Abstract: | The evaporation of single triethyl phosphate (TEP) micro-droplets containing a high molecular weight polymer, poly(methyl
methacrylate) (PMAA), was inves-tigated using an electrodynamic trap and light scattering measurements to explore the suppression
of evaporation by the additive. Pure-component evaporation rates were measured to determine the vapor pressure over a range
of temperatures, and the polymer was found to significantly decrease the evaporation rate. A numerical solution of the problem
of simultaneous solvent evaporation and polymer diffusion within the droplet indicated a rapid build-up of PMMA at the surface
of the drop, but vapor/liquid thermodynamic considerations alone do not account for the observed reduction in the evaporation
rate for the droplets containing PMMA. After significant evaporation of TEP occurred, the ultra-low evaporation rate was measured
using changes in the Raman spectra associated with morphology-dependent resonances. The evaporation in this regime appears
to be controlled by the rate of solvent molecules diffusing through the polymer matrix.
Received: 17 June 1997 Accepted: 24 October 1997 |
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Keywords: | Microdroplets polymer solutions triethyl phosphate poly(methyl methacrylate) electrodynamic balance |
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