| 聚合物对锆钛酸铅纳米晶须形貌的影响 |
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| 引用本文： | 杨小勤,赵永男,杨扬.聚合物对锆钛酸铅纳米晶须形貌的影响[J].无机化学学报,2006,22(12):2193-2196. |
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| 作者姓名： | 杨小勤 赵永男 杨扬 |
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| 作者单位： | 天津工业大学材料化工学院,天津,300160 |
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| 基金项目： | 教育部留学回国人员科研启动基金;天津市自然科学基金 |
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| 摘 要： | 本工作以(C4H9O)4Ti、Pb(NO3)2和ZrOCl2·8H2O为主要原料，采用改进的水热方法合成了锆钛酸铅(PZT)纳米晶须，并考察了聚合物对锆钛酸铅晶体形貌的影响。结果表明，聚合物对于控制晶体的取向生长起着关键性作用。另外还初步探讨了不同浓度以及不同聚合物对晶体形貌的影响机理，认为聚合物起着覆盖和螯合的作用，进而影响晶体的取向生长趋势，形成纳米线。
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| 关 键 词： | 水热合成 PZT纳米晶须 聚合物 |
| 文章编号： | 1001-4861(2006)120-2193-04 |
| 收稿时间： | 2006-07-23 |
| 修稿时间： | 2006-09-25 |
Effect of Polymer on Morphology of PZT Nanowhiskers |
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| YANG Xiao-Qin,ZHAO Yong-Nan and YANG Yang.Effect of Polymer on Morphology of PZT Nanowhiskers[J].Chinese Journal of Inorganic Chemistry,2006,22(12):2193-2196. |
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| Authors: | YANG Xiao-Qin ZHAO Yong-Nan and YANG Yang |
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| Institution: | College of Materials Science and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300160,College of Materials Science and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300160 and College of Materials Science and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300160 |
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| Abstract: | PZT nanowhiskers was hydrothermally synthesized by using (C4H9O)4Ti, Pb(NO3)2 and ZrOCl2·8H2O as raw materia1s. The effect of the polymer on the morphology of PZT whiskers was also studied. The results show that the polymer play a key role in controlling the orientation growth of crystals. The mechanism of the influence of the polymer on the whisker was discussed. It is suggested that the polymer serves as chelating ligand and capping reagent, leading to orientation growth and promoting the formation of nanowires. |
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| Keywords: | hydrothermal synthesis PZT nanowhisker polymer |
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