Octa-membered Water Ring Chain Based on Sulfonic Group in Ni(Ⅱ) Complex with 2-[(E)-(2-Oxidophenyl)methyleneamino] Ethanesulfonato and 2,2'-Bipyridinyl |
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作者姓名: | ZHANG Shu-Hua LI Guang-Zhao ZHONG Fan FENG Xiao-Zhen |
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作者单位: | [1]Key Laboratory of Non-ferrous Metal Materials and Processing Technology,( Guilin University of Technology), Ministry of Education, Guilin 541004, China [2]State Key Laboratory of CoordinationChemistry, Nanjing University, Nanjing 210093, China [3]Department of Chemistry, Jinggangshan Normal College, Ji'an 343009, China |
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基金项目: | Supported by the Key Laboratocy of Non-ferrous Metal Materials and New Processing Technology, Milfistry of Education and the State Key Laboratory of Coordination Chemislry |
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摘 要: | The title compound, [Ni(tssb)(2,2-bipy)2].5(H2O) 1 (tssbH2 =2-[(E)-(2-oxido- phenyl)methyleneamino]ethanesulfonato, 2,2-bipy = 2,2'-bipyridinyl), belongs to orthorhombic, space group Pbcn with a = 20.3983(18), b = 17.6929(15), c = 17.0897(15) nm, V= 6167.8(9) nm^3, Mr= 688.38, Z = 8, De = 1.481 g.cm^-3, F(000) = 2880,μ = 0.758 mm-1 and S =1.099. Each NiIr atom is six-coordinated by one N and one O atoms from one tssb^2- anion and four N atoms from two 2,2-bipy ligands to give a distorted octahedral geometry. Noticeably, there exists a rare octa-mem- bered water ring which presents a 1D chain by sulfonic group.
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关 键 词: | 镍(Ⅱ) 络合物 甲基 化学分析 |
收稿时间: | 2007-01-19 |
修稿时间: | 2007-06-11 |
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