冷却水中异味污染物的LC-GC/FTIR联用分析

利用在线式高效液相色谱－毛细管气相色谱／傅里叶变换红光谱联用方法分析了某冷却水中的异味污染物。结果表明，污染系苯酚类化合物所致。

Analysis of Odoriferous Pollutants in Cooling Water by on-line LC-GC/FTIR Method

The integration of two dimensional chromatography system (LC-GC) has ability for clean-up, enrichment, pre-separation and high resolution separation for the sample. The coupling of LC-GC with FTIR can notably improve the detection ability of conventional (light pipe) GC/FTIR system. The interface of LC-GC system employs retention gap technique (15 m x 0.53 mm i.d. retention gap column and 4 m x 0.25 mm i.d. precolumn) with on-column injection and partially concurrent solvent evaporation with early vapor exit. The applicability of the method is demonstrated by the analysis of odoriferous pollutants (phenolic compounds) in the cooling water with 15 cm x 2 mm i.d. silica LC column and 35 m x 0.25 mm i.d. OV-101GC column under the conditions of haxane/dichloromethane (80:20) as the mobile phase (0.3 mL/min) of LC, N2 as the carrier gas in GC and solvent evaporation temperature 80 degrees C, inlet pressure of 0.2 MPa etc. The method of on-line coupled LC-GC/FTIR is a reliable analytical tool for microcomponents in complex mixtures.