Ion transfer of bromophenol blue across liquid-liquid interfaces |
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| Authors: | Erkang Wang Zhisheng Sun |
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| Affiliation: | Changchun Institute of Applied Chemistry, Academia Sinica, Changchum, Jilin 130021 People''s Republic of China;Department of Electro-Optical Engineering, National Taipei University of Technology, Taipei 10608, Taiwan;LAQV, REQUIMTE, Department of Chemical Sciences, Laboratory of Applied Chemistry, Faculty of Pharmacy, Porto University, Rua de Jorge Viterbo Ferreira, 228, 4050-313 Porto, Portugal;Electroanalytical Chemistry Research Laboratory, Department of Analytical Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran |
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| Abstract: | The ion transfer of the acidic dye bromophenol blue (BPB) at the interfaces of water/nitrobenzene (W/NB), water/1,2-dichloroethane (W/1,2-DCE) and water/(nitrobenzene+chlorobenzene) (W/(NB +CB)) was studied in detail by cyclic voltammetry (CV), chronopotentiometry with linear current scanning (CLC), controlled potential electrolysis and UV spectroscopic methods. Using controlled potential electrolysis, we observed successfully the transfer process of BPB across the W/NB interface from the colour changes of BPB in two different phases. The proposed transfer mechanism for BPB is proved to be reasonable using UV spectroscopy of the product of the electrolysis. The standard potential differences Δowo and the standard Gibbs energies of the BPB transfer from water to some organic solvents were calculated. The dissociation constants of BPB obtained were quite close to the literature values. |
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